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The research presented in this study aims to tackle a pivotal challenge in solar energy technologies: how to sustain energy production when direct sunlight is not readily available. By introducing a novel photothermal radiator that effectively harnesses diffused light through plasmonic Fe₃O₄@Cu2-xS nanoparticles, we seek to offer a sustainable solution for maintaining comfortable indoor temperatures without heavy reliance on traditional solar sources. Our approach involves the use of UV and IR lights to photothermally activate transparent Fe₃O₄@Cu2-xS thin films, showcasing a proactive strategy to optimize energy capture even in low-light scenarios such as cloudy days or nighttime hours. This innovative technology carries immense potential for energy-neutral buildings, paving the way to reduce dependence on external energy grids and promoting a more sustainable future for indoor heating and comfort control. The developed photothermal radiator incorporates multiple transparent thin films infused with plasmonic Fe₃O₄@Cu2-xS nanoparticles, known for their robust UV and IR absorptions driven by Localized Surface Plasmon Resonance (LSPR). Through the application of UV and IR lights, these thin films efficiently convert incident photons into thermal energy. Our experiments within a specially constructed Diffused Light Photothermal Box (DLPB), designed to simulate indoor environments, demonstrate the system's capability to raise temperatures above 50°C effectively. This pioneering photothermal radiator offers a promising pathway for sustainable heat generation in indoor spaces, harnessing ubiquitous diffused light sources to enhance energy efficiency. 

A Photothermal Solar Tunnel Radiator (PSTR) is designed and developed by employing multiple transparent photothermal glass panels (TPGP). The primary objective is to pioneer a transformative approach to achieve energy-neutral building heating utilities, exemplified by a lab-scale "Photothermal Solar Box" (PSB) exclusively heated with TPGP under natural sunlight. The PSTR presents a novel paradigm for sustainable energy, enabling direct solar energy capture through transparent glass substrates with photothermal coatings. The high transparency of Fe3O4@Cu2-xS coated glass substrates enhance efficient solar harvesting and photothermal energy generation within the Photothermal Solar Box. The system demonstrates an impressive thermal energy output, reaching up to 9.1x105 joules with 8 photothermal panels in parallel. Even under colder conditions (ambient temperature: -10 °C), with accelerated heat loss, the interior temperatures of the PSB with partial thermal insulation achieve a commendable 35 °C, showcasing effective photothermal heating in cold weather. These findings indicate the system's resilience and efficiency in harnessing solar energy under diverse conditions, including partial cloudy weather. The initiative contributes to broader sustainability goals by providing a scalable and practical alternative to traditional solar heating methods, aligning with the global mission for a cleaner, greener future. 

Among major energy conversion methods, photovoltaic (PV) solar cells have been the most popular and widely employed for a variety of applications. Although a PV solar panel has been shown as one of the most efficient green energy sources, its 2D surface solar light harvesting has reached great limitations as it requires large surface areas. There is, therefore, an increasing need to seek solar harvest in a three-dimensional fashion for enhanced energy density. In addition to a conventional 2D solar panel in the x-y area, we extend another dimension of solar harvesting in the z-axis through multiple CdTe solar panels arranged in parallel. The high transparency allows sunlight to partially penetrate multiple solar panels, resulting in significantly increased solar harvesting surface area in a 3D fashion. The advantages of the 3D multi-panel solar harvesting system include: i) enlarged solar light collecting surface area, therefore increased energy density, ii) the total output power from multiple panels can exceed that of the single panel, and iii) significantly reduced surface area needed for densely populated cities. With five CdTe solar panels of different transparencies in parallel, the multilayer system can produce collective output power 233% higher than that of the single solar panel under the same surface area when arranged in descending (i.e., PV panel with the highest transparency on top and lowest at bottom). The PCE of the multi-panel system has also increased 233% in descending order indicating the viability of 3D solar harvesting. The multi-panel system will dimensionally transform solar harvesting from 2D to 3D for more efficient energy generation. 

The efficiencies of photovoltaic (PV) and thermoelectric (TE) have been limited by the intrinsic properties to ~ 25 % and ~ 10 %, respectively. In current applications, photovoltaics utilizes the shorter wavelength end of the solar spectrum but suffer decreases in efficiency from heating caused by IR absorption. The novel tunable nanostructures of new hybrids eliminate this problem by directing thermal energy from longer wavelengths to the thermoelectric device. Solar light is harvested through transparent hybrid and segregated into different wavelengths: the IR is absorbed by the hybrid which is photothermally heated up to ~100 °C for the required thermoelectric temperature span; the UV/visible is directed to PV with reduced IR components, therefore significantly reducing heating. In this way, both PV and TE operate jointly by separately utilizing the full spectrum of solar light. The novel hybrid functions not only as a photothermal heater for TE but also a wavelength segregator enabling the PV and TE devices to synergistically produce electrical energy with much greater system efficiency. Also identified is the operating structural mechanism on spectral tunability and photothermal effect of the photonic hybrids.